Methyl Orange Adsorption onto Modified Extracted Cellulose from Olive Stones: Kinetics, Isotherms, Thermodynamic, Mechanism Studies, and Desorption

OS (olive stones) are a type of lingo-cellulosic biomass that is generated as a by-product in the olive oil industry. In this investigation, the EC (extracted cellulose) from the olive stones was modified with CTAB (cetyl trimethyl ammonium bromide) as cationic surfactant. The obtained MEC (modified extracted cellulose) was used as adsorbent to remove MO (methyl orange) from aqueous media. Various factors affecting the effectiveness of the adsorption process were examined and analyzed, such as the water’s pH values, the adsorbent dosage, the contact time, the initial MO dye concentration, and the ionic strength. The kinetic and the equilibrium studies showed that this adsorption process fit to the pseudo-second-order kinetic model and the Langmuir isotherm. The optimum adsorbed amount was about 76.92 mg/g. The thermodynamic study revealed that the adsorption was spontaneous and exothermic with an increase in the randomness.

Research article

Ridha Lafi
Walid Mabrouk
Abdullah Yahya Abdullah Al Zahrani
Amor Hafiane
Sherif M. A. S. Keshk
Imed Montasser

OS (olive stones) are a type of lingo-cellulosic biomass that is generated as a by-product in the olive oil industry. In this investigation, the EC (extracted cellulose) from the olive stones was modified with CTAB (cetyl trimethyl ammonium bromide) as cationic surfactant. The obtained MEC (modified extracted cellulose) was used as adsorbent to remove MO (methyl orange) from aqueous media. Various factors affecting the effectiveness of the adsorption process were examined and analyzed, such as the water’s pH values, the adsorbent dosage, the contact time, the initial MO dye concentration, and the ionic strength. The kinetic and the equilibrium studies showed that this adsorption process fit to the pseudo-second-order kinetic model and the Langmuir isotherm. The optimum adsorbed amount was about 76.92 mg/g. The thermodynamic study revealed that the adsorption was spontaneous and exothermic with an increase in the randomness.

Publication date
2024-07-01
Journal / proceedings
Water Conservation Science and Engineering
Publisher
Springer Science and Business Media LLC
Volume
9
Issue
2
Article number
38
DOI
10.1007/s41101-024-00269-5

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Citation

Ridha Lafi; Walid Mabrouk; Abdullah Yahya Abdullah Al Zahrani; Amor Hafiane; Sherif M. A. S. Keshk; Imed Montasser. 2024-07-01. Methyl Orange Adsorption onto Modified Extracted Cellulose from Olive Stones: Kinetics, Isotherms, Thermodynamic, Mechanism Studies, and Desorption. Water Conservation Science and Engineering. https://doi.org/10.1007/s41101-024-00269-5

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Prof. Sherif M. A. S. Keshk
ExpertScientist

Prof. Sherif M. A. S. Keshk

Senior Researcher in Polymer Materials, Nanocomposites and Sustainable Materials Engineering

Sherif Keshk specialises in polymer materials, nanocomposites and sustainable materials engineering.

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ISSN
2366-3340, 2364-5687

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Related researchers

Prof. Sherif M. A. S. Keshk
ExpertScientist

Prof. Sherif M. A. S. Keshk

Senior Researcher in Polymer Materials, Nanocomposites and Sustainable Materials Engineering

Sherif Keshk specialises in polymer materials, nanocomposites and sustainable materials engineering.

View details