Dual‑functionalized sulfonated poly (arylene ether sulfone) membranes with sulfonamide crosslinks and octyl grafts for intermediate‑temperature proton exchange fuel cells

Fluorine‐free proton exchange membranes are increasingly required to replace perfluoro sulfonic acid (PFAS) materials in hydrogen fuel cells operating at low humidity and moderate temperatures. In this work, a one‐step grafting–crosslinking strategy was used to fabricate a dual‐functionalized sulfonated poly(ether sulfone) membrane (SPESOD) incorporating hydrophobic octylamine side chains and sulfonamide crosslinks via NH2PES.

Research article

Qana A. Alsulami
Walid Mabrouk
Sherif M. A. S. Keshk

Fluorine‐free proton exchange membranes are increasingly required to replace perfluoro sulfonic acid (PFAS) materials in hydrogen fuel cells operating at low humidity and moderate temperatures. In this work, a one‐step grafting–crosslinking strategy was used to fabricate a dual‐functionalized sulfonated poly(ether sulfone) membrane (SPESOD) incorporating hydrophobic octylamine side chains and sulfonamide crosslinks via NH2PES.

Publication date
2026-06-15
Journal / proceedings
Ionics
Publisher
Springer Science and Business Media LLC
Volume
32
Issue
8
Pages
8397-8411
DOI
10.1007/s11581-026-07268-7

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Citation

Qana A. Alsulami; Walid Mabrouk; Sherif M. A. S. Keshk. 2026-06-15. Dual‑functionalized sulfonated poly (arylene ether sulfone) membranes with sulfonamide crosslinks and octyl grafts for intermediate‑temperature proton exchange fuel cells. Ionics. 8397-8411. https://doi.org/10.1007/s11581-026-07268-7

BECOME contributors

Prof. Sherif M. A. S. Keshk
ExpertScientist

Prof. Sherif M. A. S. Keshk

Senior Researcher in Polymer Materials, Nanocomposites and Sustainable Materials Engineering

Sherif Keshk specialises in polymer materials, nanocomposites and sustainable materials engineering.

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ISSN
0947-7047, 1862-0760

Scientific authors are listed above. Content record maintained by BECOME.

Related researchers

Prof. Sherif M. A. S. Keshk
ExpertScientist

Prof. Sherif M. A. S. Keshk

Senior Researcher in Polymer Materials, Nanocomposites and Sustainable Materials Engineering

Sherif Keshk specialises in polymer materials, nanocomposites and sustainable materials engineering.

View details